Categories
Fragranol
- CAS: 30346-21-5
- Purity: 99%
- China cas 30346-21-5 manufacturer wholesale Fragranol at affordable price
China cas 30346-21-5 manufacturer wholesale Fragranol at affordable price
- Molecular Formula: C10H18O
- Molecular Weight: 154.252
- PSA: 20.23000
- LogP: 2.36120
30346-21-5 Relevant articles
Catalytic enantioselective synthesis of benzocyclobutenols and cyclobutanolsviaa sequential reduction/C-H functionalization
Chen, Jun,Li, Chunyu,Lu, Ping,Shi, Zhan
, p. 10598 - 10604 (2021/08/20)
We report here a sequential enantioselec...
Ring-Expansion Induced 1,2-Metalate Rearrangements: Highly Diastereoselective Synthesis of Cyclobutyl Boronic Esters
Abell, Joseph C.,Aggarwal, Varinder K.,Fasano, Valerio,Hari, Durga Prasad
, p. 5515 - 5520 (2020/04/10)
The broad synthetic utility of organobor...
A highly stereocontrolled formal total synthesis of (±)- and of (-)-grandisol by 1,4-conjugated addition of organocopper reagents to cyclobutylidene derivatives
Bernard, Angela M.,Frongia, Angelo,Ollivier, Jean,Piras, Pier Paolo,Secci, Francesco,Spiga, Marco
, p. 4968 - 4974 (2008/02/01)
Starting from suitable cyclopropanes, a ...
Stereospecific palladium(0)-catalyzed reduction of 2-cyclobutylidenepropyl esters. A versatile preparation of diastereomeric monoterpenoids: (±)-fragranol and (±)-grandisol
Bernard, Angela M.,Frongia, Angelo,Secci, Francesco,Delogu, Giovanna,Ollivier, Jean,Piras, Pier P.,Salaün, Jacques
, p. 9433 - 9440 (2007/10/03)
Mixtures of (E and Z)-2-cyclobutylidenep...
30346-21-5 Process route
-
-
29578-30-1,53171-67-8,55760-16-2,68225-43-4,68225-44-5
cis-1-methyl-2-(1-methylethenyl)-cyclobutaneacetic acid
-
-
26532-22-9,28117-21-7,30346-21-5,30820-22-5,51937-29-2,54088-78-7,68225-45-6,108645-56-3
grandisol
| Conditions | Yield |
|---|---|
|
With
lithium aluminium tetrahydride;
In
diethyl ether;
Ambient temperature;
|
82%
|
|
With
lithium aluminium tetrahydride;
In
diethyl ether;
Ambient temperature;
|
82%
|
|
With
lithium aluminium tetrahydride;
In
diethyl ether;
Ambient temperature;
|
-
-
(1RS,2RS)-2-{1-methyl-2-[1-(methylsulfonyl)-1-(phenylsulfonyl)ethyl]cyclobutyl}ethanol
-
-
26532-22-9,28117-21-7,30346-21-5,30820-22-5,51937-29-2,54088-78-7,68225-45-6,108645-56-3
grandisol
| Conditions | Yield |
|---|---|
|
With
methyllithium; lithium bromide;
In
tetrahydrofuran; diethyl ether;
at 0 ℃;
for 1h;
|
56.6%
|
30346-21-5 Upstream products
-
20763-19-3
(methoxymethylene)triphenylphosphorane
-
56102-13-7
2-[(1S,2R)-2-(2-Benzenesulfinyl-1-methyl-ethyl)-1-methyl-cyclobutyl]-ethanol
-
55760-16-2
2-isopropenyl-1-methyl-1-cyclobutaneacetic acid
-
63623-52-9
((1S,2S)-2-Isopropenyl-1-methyl-cyclobutyl)-acetaldehyde